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Pes spectrum. The peaks in a pes spectrum correspond to electrons in different subshells of an atom. Photoelectron spectrophotometers use high energy radiation uv or x rays to eject electrons from an atom the photoelectron spectrophotometer inputs only one type of radiation with a specific energy because electrons within an atom are in different energy levels different electrons can require different amounts of energy to eject. Pes spectra the photoelectron spectrum is a plot of the relative number of electrons emitted versus their ionization energy. Photoelectron spectroscopy pes is the energy measurements of photoelectrons emitted from solids gases or liquids by the photoelectric effect.
The peaks with the lowest binding energies correspond to valence electrons while the peaks with higher binding energies correspond to core electrons. Depending on the source of ionization energy pes can be divided accordingly into ultraviolet photoelectron spectroscopy ups and x ray photoelectron spectroscopy xps. Photoemission spectroscopy pes also known as photoelectron spectroscopy refers to energy measurement of electrons emitted from solids gases or liquids by the photoelectric effect in order to determine the binding energies of electrons in the substance. The pes spectrum has a single band that corresponds to the ionization of a 1sg electron.
In the diagram below the x axis is labeled high to low energies so that you think about the xy intersect as being the nucleus. A pes spectrum is a graph of photoelectron count vs. Transcript in the analytical technique of photoelectron spectroscopy pes a sample is ionized using high energy radiation and the kinetic energies of the ejected electrons called photoelectrons are measured. From this we can determine the binding or ionization energy of each electron in the atom or molecule.
Each electron in an atom or molecule can be liberated from that molecule if provided with enough energy from electromagnetic em radiation light. Photoelectron spectroscopy pes is an important method for probing the energy level structure of atoms and molecules.
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